Given a data setup like this:
The formula in cell D2 and copied down is:
=INDEX($B$2:$B$28,MATCH(1,INDEX(($A$2:$A$28=LARGE($A$2:$A$28,ROWS(D$1:D1)))*(COUNTIF(D$1:D1,$B$2:$B$28)=0),),0))
This formula will work even if there are tied OPS scores among players.