[excel] How to align matching values in two columns in Excel, and bring along associated values in other columns

assuming the item numbers are unique, a VLOOKUP should get you the information you need.

first value would be =VLOOKUP(E1,A:B,2,FALSE), and the same type of formula to retrieve the second value would be =VLOOKUP(E1,C:D,2,FALSE). Wrap them in an IFERROR if you want to return anything other than #N/A if there is no corresponding value in the item column(s)