As has been mentioned by others, std::unique_lock tracks the locked status of the mutex, so you can defer locking until after construction of the lock, and unlock before destruction of the lock. std::lock_guard does not permit this.
There seems no reason why the std::condition_variable wait functions should not take a lock_guard as well as a unique_lock, because whenever a wait ends (for whatever reason) the mutex is automatically reacquired so that would not cause any semantic violation. However according to the standard, to use a std::lock_guard with a condition variable you have to use a std::condition_variable_any instead of std::condition_variable.
Edit: deleted "Using the pthreads interface std::condition_variable and std::condition_variable_any should be identical". On looking at gcc's implementation: