[excel] Change the column label? e.g.: change column "A" to column "Name"

I would like to present another answer to this as the currently accepted answer doesn't work for me (I use LibreOffice). This solution should work in Excel, LibreOffice and OpenOffice:

First, insert a new row at the beginning of the sheet. Within that row, define the names you need: new row

Then, in the menu bar, go to View -> Freeze Cells -> Freeze First Row. It'll look like this now: new top row

Now whenever you scroll down in the document, the first row will be "pinned" to the top: new behaviour