I have written lot of scripts to automate daily backups etc. Previously I used XCopy and then moved to Robocopy. Anyways Robocopy and XCopy both are frequently used in terms of file transfers in Windows. Robocopy stands for Robust File Copy. All type of huge file copying both these commands are used but Robocopy has added options which makes copying easier as well as for debugging purposes.
Having said that lets talk about features between these two.
Robocopy becomes handy for mirroring or synchronizing directories. It also checks the files in the destination directory against the files to be copied and doesn't waste time copying unchanged files.
Just like myself, if you are into automation to take daily backups etc, "Run Hours - /RH" becomes very useful without any interactions. This is supported by Robocopy. It allows you to set when copies should be done rather than the time of the command as with XCopy. You will see robocopy.exe process in task list since it will run background to monitor clock to execute when time is right to copy.
Robocopy supports file and directory monitoring with the "/MON" or "/MOT" commands.
Robocopy gives extra support for copying over the "archive" attribute on files, it supports copying over all attributes including timestamps, security, owner, and auditing information.
Hope this helps you.