I've had to do a verification of a letsencrypt certificate and I did it like this:
Issue this command:
$ openssl verify -CAfile letsencrypt-root-cert/isrgrootx1.pem.txt -untrusted letsencrypt-intermediate-cert/letsencryptauthorityx3.pem.txt /etc/letsencrypt/live/sitename.tld/cert.pem
/etc/letsencrypt/live/sitename.tld/cert.pem: OK