Per the documentation you posted, and this blog post - there's no difference when declaring the primitive between an unsigned int/long and a signed one. The "new support" is the addition of the static methods in the Integer and Long classes, e.g. Integer.divideUnsigned. If you're not using those methods, your "unsigned" long above 2^63-1 is just a plain old long with a negative value.
From a quick skim, it doesn't look like there's a way to declare integer constants in the range outside of +/- 2^31-1, or +/- 2^63-1 for longs. You would have to manually compute the negative value corresponding to your out-of-range positive value.