You cannot play two animations since the attribute can be defined only once. Rather why don't you include the second animation in the first and adjust the keyframes to get the timing right?
.image {_x000D_
position: absolute;_x000D_
top: 50%;_x000D_
left: 50%;_x000D_
width: 120px;_x000D_
height: 120px;_x000D_
margin:-60px 0 0 -60px;_x000D_
-webkit-animation:spin-scale 4s linear infinite;_x000D_
}_x000D_
_x000D_
@-webkit-keyframes spin-scale { _x000D_
50%{_x000D_
transform: rotate(360deg) scale(2);_x000D_
}_x000D_
100% { _x000D_
transform: rotate(720deg) scale(1);_x000D_
} _x000D_
}
_x000D_
<img class="image" src="http://makeameme.org/media/templates/120/grumpy_cat.jpg" alt="" width="120" height="120">
_x000D_