This is a bit of a cheat but I just set a default style and then overrode it using a DataTrigger if the value is null...
<Style>
<!-- Highlight for Reviewed (Default) -->
<Setter Property="Control.Background" Value="PaleGreen" />
<Style.Triggers>
<!-- Highlight for Not Reviewed -->
<DataTrigger Binding="{Binding Path=REVIEWEDBY}" Value="{x:Null}">
<Setter Property="Control.Background" Value="LightIndianRed" />
</DataTrigger>
</Style.Triggers>
</Style>