When you need an outer join the second syntax is not always required:
Oracle:
SELECT a.foo, b.foo
FROM a, b
WHERE a.x = b.x(+)
MSSQLServer (although it's been deprecated in 2000 version)/Sybase:
SELECT a.foo, b.foo
FROM a, b
WHERE a.x *= b.x
But returning to your question. I don't know the answer, but it is probably related to the fact that a join is more natural (syntactically, at least) than adding an expression to a where clause when you are doing exactly that: joining.