As others have said, you can use the dependency:analyze goal to find which dependencies are used and declared, used and undeclared, or unused and declared. You may also find dependency:analyze-dep-mgt useful to look for mismatches in your dependencyManagement section.
You can simply remove unwanted direct dependencies from your POM, but if they are introduced by third-party jars, you can use the <exclusions>
tags in a dependency to exclude the third-party jars (see the section titled Dependency Exclusions for details and some discussion). Here is an example excluding commons-logging from the Spring dependency:
<dependency>
<groupId>org.springframework</groupId>
<artifactId>spring</artifactId>
<version>2.5.5</version>
<exclusions>
<exclusion>
<groupId>commons-logging</groupId>
<artifactId>commons-logging</artifactId>
</exclusion>
</exclusions>
</dependency>