You may want to use:
SELECT Name, 'Unpaid' AS Status FROM table;
The SELECT
clause syntax, as defined in MSDN: SELECT Clause (Transact-SQL), is as follows:
SELECT [ ALL | DISTINCT ]
[ TOP ( expression ) [ PERCENT ] [ WITH TIES ] ]
<select_list>
Where the expression
can be a constant, function, any combination of column names, constants, and functions connected by an operator or operators, or a subquery.