You do not even need lists if your "number" values are all of the same mode. If I take Dirk Eddelbuettel's example:
> foo <- c(12, 22, 33)
> names(foo) <- c("tic", "tac", "toe")
> foo
tic tac toe
12 22 33
> names(foo)
[1] "tic" "tac" "toe"
Lists are only required if your values are either of mixed mode (for example characters and numbers) or vectors.
For both lists and vectors, an individual element can be subsetted by name:
> foo["tac"]
tac
22
Or for a list:
> foo[["tac"]]
[1] 22