The Activity
which you want it to be the very first screen if your app is opened, then mention it as LAUNCHER in the intent category and remaining activities mention Default in intent category.
For example :- There is 2 activity A and B
The activity A is LAUNCHER so make it as LAUNCHER in the intent Category and B is child for Activity A so make it as DEFAULT.
<application android:icon="@drawable/icon" android:label="@string/app_name">
<activity android:name=".ListAllActivity"
android:label="@string/app_name">
<intent-filter>
<action android:name="android.intent.action.MAIN" />
<category android:name="android.intent.category.LAUNCHER" />
</intent-filter>
</activity>
<activity android:name=".AddNewActivity" android:label="@string/app_name">
<intent-filter>
<action android:name="android.intent.action.MAIN" />
<category android:name="android.intent.category.DEFAULT" />
</intent-filter>
</activity>
</application>