Ok. As the other answerers explained, a stack is a last-in, first-out data structure. You add an element to the top of the stack with a Push operation. You take an element off the top with a Pop operation. The elements are removed in reverse order to the order they were put inserted (hence Last In, First Out). For example, if you push the elments 1,2,3 in that order, the number 3 will be at the top of the stack. A Pop operation will remove it (it was the last in) and leave 2 at the top of the stack.
Regarding the rest of the lecture, the lecturer tried to describe a stack-based machine that evaluates arithmetic expressions. The machine operates by continuously popping 3 elements from the top of the stack. The first two elements are operands and the third is an operator (+, -, *, /). It then applies this operator on the operands, and pushes the result onto the stack. The process continues until there is only one element on the stack, which is the value of the expression.
So, suppose we begin by pushing the values "+/*23-21*5-41" in left-to-right order onto the stack. We then pop 3 elements from the top. The last in is first out, which means the first 3 element are "1", "4", and "-" in that order. We push the number 3 (the result of 4-1) onto the stack, then pop the three topmost elements: 3, 5, *. Push the result, 15, onto the stack, and so on.