From the RFC (3023), under section 3, XML Media Types:
If an XML document -- that is, the unprocessed, source XML document -- is readable by casual users, text/xml is preferable to application/xml. MIME user agents (and web user agents) that do not have explicit support for text/xml will treat it as text/plain, for example, by displaying the XML MIME entity as plain text. Application/xml is preferable when the XML MIME entity is unreadable by casual users.
(emphasis mine)