I think the best way is to store them in some yml file and then load that file using this command in intializer file
APP_CONFIG = YAML.load_file("#{Rails.root}/config/CONFIG.yml")[Rails.env].to_hash
you can easily access environment related config variables.
Your Yml file key value structure:
development:
app_key: 'abc'
app_secret: 'abc'
production:
app_key: 'xyz'
app_secret: 'ghq'