Microsoft Visual Studio Express
It's a full IDE, with powerful debugging tools, syntax highlighting, etc.
Get gcc for Windows . However, you will have to install MinGW as well.
You can use Visual Studio 2010 express edition as well. Link here
If you are familiar with gcc, as you indicated in the question, you can install MinGW, which will set a linux-like compile environment in Win7. Otherwise, Visual Studio 2010 Express is the best choice.
You can get MinGW (as others have suggested) but I would recommend getting a simple IDE (not VS Express). You can try Dev C++ http://www.bloodshed.net/devcpp.html Its a simple IDE for C/C++ and uses MinGW internally. In this you can write and compile single C files without creating a full-blown "project".
Compiling Programs on Windows 7:
You have to download configured Borland Compiler from http://www.4shared.com/get/Gs41_5yA/borland_for_graphics.html or http://dwij.co.in/graphics-c-programming-for-windows-7-borland-compiler/.
Put your Borland’s ‘bin’ folder into Environmental Variables.
Now go inside folder ‘bin’ & edit file bcc32.cfg as per your folder structure. This file contains settings of headers & libraries.
-I"D:\Borland\include;"
-L"D:\Borland\lib;D:\Borland\Lib\PSDK"
Now create any C/C++ Program say myprogram.cpp
Use following command to compile this bunch of code:
F:\>bcc32 myprogram.cpp
Source: Stackoverflow.com