You'll want to change the extension of your css file from .css.scss
to .css.scss.erb
and do:
background-image:url(<%=asset_path "admin/logo.png"%>);
You may need to do a "hard refresh" to see changes. CMD+SHIFT+R on OSX browsers.
In production, make sure
rm -rf public/assets
bundle exec rake assets:precompile RAILS_ENV=production
happens upon deployment.