If you have a pristine repo (or HEAD isn't set)[1] you could simply
rm .git/index
Of course, this will require you to re-add the files that you did want to be added.
[1] Note (as explained in the comments) this would usually only happen when the repo is brand-new ("pristine") or if no commits have been made. More technically, whenever there is no checkout or work-tree.
Just making it more clear :)