Strings in C are represented as arrays of characters.
char *p = "String";
You are declaring a pointer that points to a string stored some where in your program (modifying this string is undefined behavior) according to the C programming language 2 ed.
char p2[] = "String";
You are declaring an array of char initialized with the string "String" leaving to the compiler the job to count the size of the array.
char p3[5] = "String";
You are declaring an array of size 5 and initializing it with "String". This is an error be cause "String" don't fit in 5 elements.
char p3[7] = "String";
is the correct declaration ('\0' is the terminating character in c strings).