.pyz - Python script archive (PEP 441); this is a script containing compressed Python scripts (ZIP) in binary form after the standard Python script header
.pywz - Python script archive for MS-Windows (PEP 441); this is a script containing compressed Python scripts (ZIP) in binary form after the standard Python script header
.py[cod] - wildcard notation in ".gitignore" that means the file may be ".pyc", ".pyo", or ".pyd".
.pth - a path configuration file; its contents are additional items (one per line) to be added to sys.path. See site module.