You can open a command prompt and do a
route print
and see your current routing table.
You can modify it by
route add d.d.d.d mask m.m.m.m g.g.g.g
route delete d.d.d.d mask m.m.m.m g.g.g.g
route change d.d.d.d mask m.m.m.m g.g.g.g
these seem to work
I run a ping d.d.d.d -t change the route and it changes. (my test involved routing to a dead route and the ping stopped)