Just as a regular SELECT
?
SELECT
Val1, Val2, Val3,
Total = Val1 + Val2 + Val3
FROM dbo.Emp
Or do you want to determine that total and update the table with those values?
UPDATE dbo.Emp
SET Total = Val1 + Val2 + Val3
If you want to have this total be current at all times - you should have a computed column in your table:
ALTER TABLE dbo.Emp
ADD CurrentTotal AS Val1 + Val2 + Val3 PERSISTED
Then you will always get the current total - even if the values change:
SELECT
Val1, Val2, Val3, CurrentTotal
FROM dbo.Emp