You can reorder the columns with [, or present the columns in the order that you want.
d <- data.frame(a=1:4, b=5:8, c=9:12)
target <- which(names(d) == 'b')[1]
cbind(d[,1:target,drop=F], data.frame(d=12:15), d[,(target+1):length(d),drop=F])
a b d c
1 1 5 12 9
2 2 6 13 10
3 3 7 14 11
4 4 8 15 12