This works, been tested...
SELECT n.c.value('OrganizationReportReferenceIdentifier[1]','varchar(128)') AS 'OrganizationReportReferenceNumber',
n.c.value('(OrganizationNumber)[1]','varchar(128)') AS 'OrganizationNumber'
FROM Batches t
Cross Apply RawXML.nodes('/GrobXmlFile/Grob/ReportHeader') n(c)