In case people are searching how to do it in BigQuery:
An underscore "_" matches a single character or byte.
You can escape "\", "_", or "%" using two backslashes. For example, "\%". If you are using raw strings, only a single backslash is required. For example, r"\%".
WHERE mycolumn LIKE '%\\_%'
Source: https://cloud.google.com/bigquery/docs/reference/standard-sql/operators