it's well documented here:
https://cwiki.apache.org/confluence/display/TOMCAT/Connectors#Connectors-Q6
How do I bind to a specific ip address? - "Each Connector element allows an address property. See the HTTP Connector docs or the AJP Connector docs". And HTTP Connectors docs:
http://tomcat.apache.org/tomcat-7.0-doc/config/http.html
Standard Implementation -> address
"For servers with more than one IP address, this attribute specifies which address will be used for listening on the specified port. By default, this port will be used on all IP addresses associated with the server."