<role rolename="tomcat"/>
<role rolename="manager-gui"/>
<role rolename="admin-gui"/>
<role rolename="manager-script"/>
<role rolename="manager-jmx"/>
<user username="admin" password="admin" roles="tomcat,manager-gui,admin-gui,manager-script,manager-jmx"/>
Close all the session, once closed, ensure open the URL in incognito mode login again and it should start working