That depends on your definition of which disk drive Windows used to boot. I can think of 3 different answers on a standard BIOS system (who knows what an EFI system does):
2 and 3 should be easy to find - I'm not so sure about 1. Though you can raw disk read to find an MBR, that doesn't mean it's the BIOS boot device this time or even next time (you could have multiple disks with MBRs).
You really can't even be sure that the PC was started from a hard drive - it's perfectly possible to boot Windows from a floppy. In that case, both 1 and 2 would technically be a floppy disk, though 3 would remain C:\Windows.
You might need to be a bit more specific in your requirements or goals.