I couldn't get Facebook to pick the right image from a specific post, so I did what's outlined on this page:
https://webapps.stackexchange.com/questions/18468/adding-meta-tags-to-individual-blogger-posts
In other words, something like this:
<b:if cond='data:blog.url == "http://urlofyourpost.com"'>
<meta content='http://urlofyourimage.png' property='og:image'/>
</b:if>
Basically, you're going to hard code an if statement into your site's HTML to get it to change the meta content for whatever you've changed for that one post. It's a messy solution, but it works.