If it is a Windows DLL file and your OS is Linux then use winedump:
$ winedump -j export pcre.dll
Contents of pcre.dll: 229888 bytes
Exports table:
Name: pcre.dll
Characteristics: 00000000
TimeDateStamp: 53BBA519 Tue Jul 8 10:00:25 2014
Version: 0.00
Ordinal base: 1
# of functions: 31
# of Names: 31
Addresses of functions: 000375C8
Addresses of name ordinals: 000376C0
Addresses of names: 00037644
Entry Pt Ordn Name
0001FDA0 1 pcre_assign_jit_stack
000380B8 2 pcre_callout
00009030 3 pcre_compile
...