[url] URL encoding the space character: + or %20?

I would recommend %20.

Are you hard-coding them?

This is not very consistent across languages, though. If I'm not mistaken, in PHP urlencode() treats spaces as + whereas Python's urlencode() treats them as %20.

EDIT:

It seems I'm mistaken. Python's urlencode() (at least in 2.7.2) uses quote_plus() instead of quote() and thus encodes spaces as "+". It seems also that the W3C recommendation is the "+" as per here: http://www.w3.org/TR/html4/interact/forms.html#h-17.13.4.1

And in fact, you can follow this interesting debate on Python's own issue tracker about what to use to encode spaces: http://bugs.python.org/issue13866.

EDIT #2:

I understand that the most common way of encoding " " is as "+", but just a note, it may be just me, but I find this a bit confusing:

import urllib
print(urllib.urlencode({' ' : '+ '})

>>> '+=%2B+'