Similar to KyleMit answer, its possible to select directly the tables used by SP_WHO2, although I think it's only need dbo.sysprocesses table.
If someone open this SP, it can understand what it does. This is my best select to have a similar output as SP_WHO2
select convert(char(5),sp.spid) as SPID
, CASE lower(sp.status)
When 'sleeping' Then lower(sp.status)
Else upper(sp.status)
END as Status
, convert(sysname, rtrim(sp.loginame)) as LOGIN
, CASE sp.hostname
When Null Then ' .'
When ' ' Then ' .'
Else rtrim(sp.hostname)
END as HostName
, CASE isnull(convert(char(5),sp.blocked),'0')
When '0' Then ' .'
Else isnull(convert(char(5),sp.blocked),'0')
END as BlkBy
, case when sp.dbid = 0 then null when sp.dbid <> 0 then db_name(sp.dbid) end as DBName
, sp.cmd as Command
, sp.cpu as CPUTime
, sp.physical_io as DiskIO
, sp.last_batch as LastBatch
, sp.program_name as ProgramName
from master.dbo.sysprocesses sp (nolock)
;
Over this select, you can select the fields you need and have the order you want.