Since applications aren't allowed to change many of the phone settings, you can open a settings activity just like another application.
Look at you LogCat output after you actually modified the setting manually:
INFO/ActivityManager(1306): Starting activity: Intent { act=android.intent.action.MAIN cmp=com.android.settings/.DevelopmentSettings } from pid 1924
Then use this to display the settings page from your app:
String SettingsPage = "com.android.settings/.DevelopmentSettings";
try
{
Intent intent = new Intent(Intent.ACTION_MAIN);
intent.setComponent(ComponentName.unflattenFromString(SettingsPage));
intent.addCategory(Intent.CATEGORY_LAUNCHER );
startActivity(intent);
}
catch (ActivityNotFoundException e)
{
log it
}