Join on one-to-many relation in JPQL looks as follows:
select b.fname, b.lname from Users b JOIN b.groups c where c.groupName = :groupName
When several properties are specified in select clause, result is returned as Object[]:
Object[] temp = (Object[]) em.createNamedQuery("...")
.setParameter("groupName", groupName)
.getSingleResult();
String fname = (String) temp[0];
String lname = (String) temp[1];
By the way, why your entities are named in plural form, it's confusing. If you want to have table names in plural, you may use @Table to specify the table name for the entity explicitly, so it doesn't interfere with reserved words:
@Entity @Table(name = "Users")
public class User implements Serializable { ... }