If you have no FIRST/FIRST conflicts and no FIRST/FOLLOW conflicts, your grammar is LL(1).
An example of a FIRST/FIRST conflict:
S -> Xb | Yc
X -> a
Y -> a
By seeing only the first input symbol a, you cannot know whether to apply the production S -> Xb or S -> Yc, because a is in the FIRST set of both X and Y.
An example of a FIRST/FOLLOW conflict:
S -> AB
A -> fe | epsilon
B -> fg
By seeing only the first input symbol f, you cannot decide whether to apply the production A -> fe or A -> epsilon, because f is in both the FIRST set of A and the FOLLOW set of A (A can be parsed as epsilon and B as f).
Notice that if you have no epsilon-productions you cannot have a FIRST/FOLLOW conflict.