Here is a piece of my Android app's code:
This app is able to communicate with a HTTP get-post model between a servlet running on a server and an Android device plugged in USB-Debuggable mode (because the app was in developing progress).
I also can run the app over Wi-Fi when the server, Tomcat Apache 7, running on (when the app development was finished).
To get the IP address of yours
ipconfig
In the list, IPv4 Address is your IP.