For starters:
<p align='center'>
<table width='100%'>
<tr>
<td align='center'><form><input type=submit value="click me" style="width:100%"></form></td>
</tr>
</table>
</p>
Note, if the width of the input button is 100%, you wont need the attribute "align='center'" anymore.
This would be the optimal solution:
<p align='center'>
<table width='100%'>
<tr>
<td><form><input type=submit value="click me" style="width:100%"></form></td>
</tr>
</table>
</p>