I've found the following "cheat" to work very neatly and error-free
> dimnames <- list(time=c(0, 0.5, 1), name=c("C_0", "C_1"))
> mat <- matrix(data, ncol=2, nrow=3, dimnames=dimnames)
> head(mat, 2) #this returns the number of rows indicated in a data frame format
> df <- data.frame(head(mat, 2)) #"data.frame" might not be necessary
Et voila!