webRTC or websockets? Why not use both.
When building a video/audio/text chat, webRTC is definitely a good choice since it uses peer to peer technology and once the connection is up and running, you do not need to pass the communication via a server (unless using TURN).
When setting up the webRTC communication you have to involve some sort of signaling mechanism. Websockets could be a good choice here, but webRTC is the way to go for the video/audio/text info. Chat rooms is accomplished in the signaling.
But, as you mention, not every browser supports webRTC, so websockets can sometimes be a good fallback for those browsers.