Right now, there is no option to select the parent of an element in CSS (not even CSS3). But with CSS4, the most important news in the current W3C draft is the support for the parent selector.
$ul li:hover{
background: #fff;
}
Using the above, when hovering an list element, the whole unordered list will be highlighted by adding a white background to it.
Official documentation: https://www.w3.org/TR/2011/WD-selectors4-20110929/#overview (last row).