For Java, from a command line:
java -version
will indicate whether it's 64-bit or not.
Output from the console on my Ubuntu box:
java version "1.6.0_12-ea"
Java(TM) SE Runtime Environment (build 1.6.0_12-ea-b03)
Java HotSpot(TM) 64-Bit Server VM (build 11.2-b01, mixed mode)
IE will indicate 64-bit versions in the About dialog, I believe.