You can use SoapUI: http://www.soapui.org/ This is a generally handy program. Make a new project, connect to the WSDL link, then right click on the project and say "Show interface viewer". Under "Schemas" on the left you can see the XSD.
SoapUI can do many things though!
Once I found an xsd link on the top of the wsdl. Like this wsdl example from the web, you can see a link xsd1. The server has to be running to see it.
<?xml version="1.0"?>
<definitions name="StockQuote"
targetNamespace="http://example.com/stockquote.wsdl"
xmlns:tns="http://example.com/stockquote.wsdl"
xmlns:xsd1="http://example.com/stockquote.xsd"
xmlns:soap="http://schemas.xmlsoap.org/wsdl/soap/"
xmlns="http://schemas.xmlsoap.org/wsdl/">
Follow these steps :
Note: SOAPUI will remove all relative paths and will save all XSDs to the same folder. Refer the screenshot :
(WHEN .wsdl is referring to .xsd/schemas using import) If you're using the WMB Tooklit (v8.0.0.4 WMB) then you can find .xsd using following steps :
Create library (optional) > Right Click , New Message Model File > Select SOAP XML > Choose Option 'I already have WSDL for my data' > 'Select file outside workspace' > 'Select the WSDL bindings to Import' (if there are multiple) > Finish.
This will give you the .xsd and .wsdl files in your Workspace (Application Perspective).
Source: Stackoverflow.com