use desc tablename
from Hive CLI or beeline to get all the column names. If you want the column names in a file then run the below command from the shell.
$ hive -e 'desc dbname.tablename;' > ~/columnnames.txt
where dbname
is the name of the Hive database where your table is residing
You can find the file columnnames.txt in your root directory.
$cd ~
$ls