The KILL SESSION
command doesn't actually kill the session. It merely asks the session to kill itself. In some situations, like waiting for a reply from a remote database or rolling back transactions, the session will not kill itself immediately and will wait for the current operation to complete. In these cases the session will have a status of "marked for kill". It will then be killed as soon as possible.
Check the status to confirm:
SELECT sid, serial#, status, username FROM v$session;
You could also use IMMEDIATE clause:
ALTER SYSTEM KILL SESSION 'sid,serial#' IMMEDIATE;
The IMMEDIATE
clause does not affect the work performed by the command, but it returns control back to the current session immediately, rather than waiting for confirmation of the kill. Have a look at Killing Oracle Sessions.
Update If you want to kill all the sessions, you could just prepare a small script.
SELECT 'ALTER SYSTEM KILL SESSION '''||sid||','||serial#||''' IMMEDIATE;' FROM v$session;
Spool the above to a .sql
file and execute it, or, copy paste the output and run it.