These sites were very helpful, almost, mergetool and difftool. I used the global configuration, but can be used by repository without problems. You just need to execute the following commands:
git config --global merge.tool kdiff3
git config --global mergetool.kdiff3.path "C:/Program Files/KDiff3/bin/kdiff3.exe"
git config --global mergetool.kdiff3.trustExitCode false
git config --global diff.guitool kdiff3
git config --global difftool.kdiff3.path "C:/Program Files/KDiff3/bin/kdiff3.exe"
git config --global difftool.kdiff3.trustExitCode false
Note that the latest version kdiff3 moved the executable from the root of the application folder C:/Program Files/KDiff3 into the bin/ folder inside the application folder. If you're using an older version, remove "bin/" from the paths above.
The use of the trustExitCode option depends on what you want to do when diff tool returns. From documentation:
git-difftool invokes a diff tool individually on each file. Errors reported by the diff tool are ignored by default. Use --trust-exit-code to make git-difftool exit when an invoked diff tool returns a non-zero exit code.