Using list comprehensions in python, you can collect an entire column of values into a list using just two lines:
df = sqlContext.sql("show tables in default")
tableList = [x["tableName"] for x in df.rdd.collect()]
In the above example, we return a list of tables in database 'default', but the same can be adapted by replacing the query used in sql().
Or more abbreviated:
tableList = [x["tableName"] for x in sqlContext.sql("show tables in default").rdd.collect()]
And for your example of three columns, we can create a list of dictionaries, and then iterate through them in a for loop.
sql_text = "select name, age, city from user"
tupleList = [{name:x["name"], age:x["age"], city:x["city"]}
for x in sqlContext.sql(sql_text).rdd.collect()]
for row in tupleList:
print("{} is a {} year old from {}".format(
row["name"],
row["age"],
row["city"]))